I. S. Akhrem, L. V. Afanas'eva, I. M. Churilova, O. I. Artyushin, N. D. Kagramanov, “Chemo- and regioselective remote functionalization of nonanamides via sp3 C–H bond cleavage under superelectrophilic conditions”, Mendeleev Commun., 2015, Volume 25, Issue 2,Pages 124

This article is cited in 5 papers

Communications

Chemo- and regioselective remote functionalization of nonanamides via sp³ C–H bond cleavage under superelectrophilic conditions

I. S. Akhrem, L. V. Afanas'eva, I. M. Churilova, O. I. Artyushin, N. D. Kagramanov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Treatment of nonanamides C₈H₁₇C(O)NR₂ (R = H or Et) with superelectrophilic complex CBr₄·2AlBr₃ under CO atmosphere followed by quenching with nucleophiles NuH cleanly gives 7-methyl-7-(Nu-carbonyl)octanamide bifunctional derivatives.

Language: English

DOI: 10.1016/j.mencom.2015.03.015

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