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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2015 Volume 25, Issue 3, Pages 171–173 (Mi mendc2339)

This article is cited in 1 paper

Communications

Rod-like derivatives of ferrocenylacetylene: syntheses and structure

V. N. Okulova, M. A. Dyadchenkoa, A. V. Churakovb, E. V. Poluninc, D. A. Lemenovskiia, H. Yud, L. Wangd, V. P. Dyadchenkoa

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
d Department of Chemistry, Zhejiang University, Hangzhou, China

Abstract: 1-Bromo-4-ferrocenylethynylbenzene was transformed into tris(4-ferrocenylethynylphenyl)boroxine and 4-ferrocenylethynylbenzoic acid, which were further converted into new rod-like ferrocenylacetylene and ferrocenylethylene derivatives. Crystal and molecular structures of tris(4-ferrocenylethynylphenyl)boroxine and (Z)-4-(2-chloro-2-ferrocenylethenyl)benzoic acid 3-(1-imidazolyl)propylamide were determined by single crystal X-ray analysis.

Language: English

DOI: 10.1016/j.mencom.2015.05.003



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