A. A. Korlyukov, M. A. Eskova, I. M. Tkachenko, Yu. N. Kononevich, O. I. Shchegolikhina, A. M. Muzafarov, “Heteroligand nickel siloxane with 4-vinylbenzyl substituents”, Mendeleev Commun., 2015, Volume 25, Issue 3,Pages <nobr>226

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Communications

Heteroligand nickel siloxane with 4-vinylbenzyl substituents

A. A. Korlyukov^a, M. A. Eskova^a, I. M. Tkachenko^b, Yu. N. Kononevich^a, O. I. Shchegolikhina^a, A. M. Muzafarov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

Abstract: A new polyherdal nickel siloxane was synthesized by the hydrolysis of triethoxy(4-vinylbenzyl)silane in the presence of NaOH and the subsequent interaction with [Ni(NH₃)₆]Cl₂. The nickel siloxane has a dimeric structure that consists of two polyhedral sandwiched pentanuclear nickel siloxane units linked by very strong O–H···O bonds into infinite chains in a crystal.

Language: English

DOI: 10.1016/j.mencom.2015.05.024