P. P. Chapala, M. V. Bermeshev, V. G. Lakhtin, A. M. Genaev, A. N. Tavtorkin, E. Sh. Finkelshtein, “[2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes”, Mendeleev Commun., 2015, Volume 25, Issue 5,Pages <nobr>344–345</nobr>

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Mendeleev Commun., 2015 Volume 25, Issue 5, Pages 344–345 (Mi mendc2402)

This article is cited in 12 papers

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[2σ + 2σ + 2π]-Cycloaddition of quadricyclane to partially methylated chlorosilylalkenes

P. P. Chapala^a, M. V. Bermeshev^a, V. G. Lakhtin^b, A. M. Genaev^c, A. N. Tavtorkin^a, E. Sh. Finkelshtein^a

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russian Federation
^c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: [2σ + 2σ + 2π]-Cycloaddition of quadricyclane to trissilylated ethenes Cl₃ _– _nMe_nSiCH=CSiMe_nCl₃ _– _n(SiMe₃ _– _nCl_n) (n = 1, 2) at 95°C affords 3,3,4-trissilylated exo-tricyclo[4.2.1.0^2,5]non-7-enes. Tetrakis(trichlorosilyl)ethene does not react with quadricyclane.

Language: English

DOI: 10.1016/j.mencom.2015.09.008

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