I. A. Efimenko, A. S. Kubasov, N. A. Ivanova, O. S. Erofeeva, L. I. Demina, “Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex”, Mendeleev Commun., 2024, Volume 34, Issue 5,Pages 748

Communications

Unusual condensation of acetone giving η³-allyl ligand in the [Pd(η³-C₆H₉O)(μ-Cl)]₂ complex

I. A. Efimenko^a, A. S. Kubasov^a, N. A. Ivanova^a, O. S. Erofeeva^a, L. I. Demina^b

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A one-step reaction was discovered giving the h³-allyl complex [Pd(h³-C₆H₉O)(μ-Cl)]₂. The formation of the substituted h³-allyl ligand in the complex occurs as a result of the condensation of acetone at room temperature in a solution containing [Pd(PhCN)₂Cl₂] and organic acids. The structure of the resulting Pdⁱⁱ complex was determined by single crystal X-ray diffraction analysis.

Keywords: acetone condensation, η³-allyl ligand, one-step reaction, η³-allyl Pdⁱⁱ complex.

Language: English

DOI: 10.1016/j.mencom.2024.09.040

	*Supplementary materials:*
		Supplementary_data_1.pdf	271.9 Kb