P. V. Markov, O. V. Turova, I. S. Mashkovsky, A. K. Khudorozhkov, V. I. Bukhtiyarov, A. Yu. Stakheev, “Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al2O3 catalysts”, Mendeleev Commun., 2015, Volume 25, Issue 5,Pages 367

This article is cited in 16 papers

Communications

Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al₂O₃ catalysts

P. V. Markov^a, O. V. Turova^a, I. S. Mashkovsky^a, A. K. Khudorozhkov^b, V. I. Bukhtiyarov^b, A. Yu. Stakheev^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: The selectivity of liquid phase semihydrogenation of diphenylacetylene for cis-stilbene is remarkably improved by increasing Pd particle size due to different structure sensitivity of alkyne and alkene hydrogenation steps.

Language: English

DOI: 10.1016/j.mencom.2015.09.017