I. L. Dalinger, A. Kh. Shakhnes, K. A. Monogarov, K. Yu. Suponitsky, A. B. Sheremetev, “Novel highly energetic pyrazoles: N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives”, Mendeleev Commun., 2015, Volume 25, Issue 6,Pages 429

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Communications

Novel highly energetic pyrazoles: N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives

I. L. Dalinger^a, A. Kh. Shakhnes^a, K. A. Monogarov^b, K. Yu. Suponitsky^c, A. B. Sheremetev^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Treatment of 1,1-dinitro-1-(3,5-dinitropyrazol-1-yl)methanide with electrophilic fluorinating or difluoroaminating agents affords the corresponding fluorodinitromethyl or (difluoroamino)dinitromethyl pyrazole derivatives. Single crystal X-ray diffraction analysis shows a remarkable high density and DSC exhibits acceptable thermal stability of the compounds.

Language: English

DOI: 10.1016/j.mencom.2015.11.010

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