P. V. Ivchenko, I. E. Nifant'ev, O. V. Smetannikov, A. A. Ivanyuk, A. V. Churakov, “Synthetic approach to 6-tert-butyl-5-methoxy-2-methylindenyl zirconium ansa-complexes, bridged in 4-position of indenyl fragment”, Mendeleev Commun., 2015, Volume 25, Issue 6,Pages 435

This article is cited in 3 papers

Communications

Synthetic approach to 6-tert-butyl-5-methoxy-2-methylindenyl zirconium ansa-complexes, bridged in 4-position of indenyl fragment

P. V. Ivchenko^ab, I. E. Nifant'ev^ab, O. V. Smetannikov^a, A. A. Ivanyuk^a, A. V. Churakov^c

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Two novel ansa-zirconocenes containing SiMe₂ bridge in non-conventional 4-position of 5-methoxy-6-tert-butylindenyl fragment have been synthesized, using TMS-protected substituted bromoindanol as a key starting compound. The structure of rac-dichloro- zirconium μ-4,4’-dimethylsilylene-bis(η⁵-6-tert-butyl-5-methoxy-2-methylinden-1-ide) was established by X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2015.11.012

	*Supplementary materials:*
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