V. O. Smirnov, A. S. Maslov, M. I. Struchkova, D. E. Arkhipov, A. D. Dilman, “Synthesis of <i>S</i>-difluoromethyl dithiocarbamates”, Mendeleev Commun., 2015, Volume 25, Issue 6,Pages <nobr>452–453</nobr>

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Mendeleev Commun., 2015 Volume 25, Issue 6, Pages 452–453 (Mi mendc2442)

This article is cited in 6 papers

Communications

Synthesis of S-difluoromethyl dithiocarbamates

V. O. Smirnov^a, A. S. Maslov^ab, M. I. Struchkova^a, D. E. Arkhipov^c, A. D. Dilman^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A method for preparation of S-difluoromethyl dithiocarbamates has been developed, which involves the treatment of secondary amines with carbon disulfide in methanol followed by S-difluoromethylation of the intermediate dithiocarbamate anion with difluorocarbene generated from (bromodifluoromethyl)trimethylsilane.

Language: English

DOI: 10.1016/j.mencom.2015.11.018

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