M. V. Tolstykh, K. P. Birin, Yu. V. Nelyubina, V. Yu. Kotov, “Reorientation of ions in contact ion pairs as a factor increasing the intensity of outer-sphere charge transfer bands”, Mendeleev Commun., 2014, Volume 24, Issue 1,Pages <nobr>47

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Communications

Reorientation of ions in contact ion pairs as a factor increasing the intensity of outer-sphere charge transfer bands

M. V. Tolstykh^a, K. P. Birin^b, Yu. V. Nelyubina^c, V. Yu. Kotov^ad

^a Institute of Natural Sciences, Moscow City Teacher’s Training University, Moscow, Russian Federation
^b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^d Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: The found increase in the extinction coefficients of ion pairs at the low dielectric permittivity of solutions in binary solvents depends on the nature of a nonpolar solvent, and it is related to not only the transformation of solvate-separated ion pairs into contact ones but also the reorientation of ions in the contact ion pairs.

Language: English

DOI: 10.1016/j.mencom.2013.12.016