A. E. Kulyashova, E. V. Mikheeva, N. A. Danilkina, I. A. Balova, “Synthesis of 2-(buta-1,3-diynyl)-<i>N,N</i>-dimethylanilines Using Reductive Methylation Step”, Mendeleev Commun., 2014, Volume 24, Issue 2,Pages <nobr>102

This article is cited in 4 papers

Communications

Synthesis of 2-(buta-1,3-diynyl)-N,N-dimethylanilines Using Reductive Methylation Step

A. E. Kulyashova, E. V. Mikheeva, N. A. Danilkina, I. A. Balova

St. Petersburg State University, St. Petersburg, Russian Federation

Abstract: Synthesis of 2-(buta-1,3-diynyl)-N,N-dimethylanilines based on reductive methylation of ortho-iodoanilines using CH2O–NaBH3CN and coupling with terminal diacetylens was developed. Altered sequence including dimethylation of 2-(buta-1,3-diynyl)anilines was also successfully achieved and gave higher overall yields in the case of anilines without acceptor substituent in the ring.

Language: English

DOI: 10.1016/j.mencom.2014.03.013

	*Supplementary materials:*
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