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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2025 Volume 35, Issue 1, Pages 73–75 (Mi mendc25)

Communications

New piperidinium surfactants containing N-ethylcarbamate fragment: aggregation properties and antimicrobial activity

R. A. Kushnazarova, D. D. Bekrenev, A. B. Mirgorodskaya, D. M. Kuznetsov, E. A. Vasilieva, L. M. Davydova, E. N. Nikitin, L. Ya. Zakharova

A. E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, 420088 Kazan, Russian Federation

Abstract: A homological series of novel piperidinium surfactants containing N-ethylcarbamate fragment and dodecyl, tetradecyl, or hexadecyl substituents was synthesized. Quantitative parameters describing their surface activity and aggregation behavior in water were determined using tensiometry and spectrophotometry. These cationic surfactants exhibit significant antimicrobial activity against several pathogenic plant strains, particularly bacteria, which increases with the transition from dodecyl to hexadecyl derivatives.

Keywords: cationic surfactants, piperidinium compounds, carbamates, aggregation behavior, solubilization, surface tension, contact angle, antimicrobial activity, fungicides.

Received: 24.06.2024
Accepted: 29.08.2024

Language: English

DOI: 10.71267/mencom.7553



© Steklov Math. Inst. of RAS, 2025