K. V. Belyaeva, L. V. Andriyankova, A. G. Mal'kina, O. G. Volostnykh, L. P. Nikitina, A. V. Afonin, I. A. Ushakov, L. V. Klyba, B. A. Trofimov, “Vinylation of trialkylamines with acyl- and cyanoacetylenes <i>via</i> C–N bond cleavage in the presence of water”, Mendeleev Commun., 2014, Volume 24, Issue 4,Pages <nobr>209

This article is cited in 6 papers

Communications

Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water

K. V. Belyaeva, L. V. Andriyankova, A. G. Mal'kina, O. G. Volostnykh, L. P. Nikitina, A. V. Afonin, I. A. Ushakov, L. V. Klyba, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Trialkylamines react with acyl- and cyanoacetylenes in the presence of water (90–100°C, 37–43h) to give functionalized N,N-dialkyl-vinylamines, the products of N-dealkylation of the starting amines, in 22–44% yields.

Language: English

DOI: 10.1016/j.mencom.2014.06.006