A. A. Mikhaylov, Yu. A. Khomutova, D. E. Arkhipov, A. A. Korlyukov, S. L. Ioffe, “ButMe2SiOTf-promoted cyanosilylation of six-membered cyclic nitronates with trialkylsilyl cyanides or tert-butyl isocyanide”, Mendeleev Commun., 2014, Volume 24, Issue 6,Pages 374

This article is cited in 8 papers

Communications

Bu^tMe₂SiOTf-promoted cyanosilylation of six-membered cyclic nitronates with trialkylsilyl cyanides or tert-butyl isocyanide

A. A. Mikhaylov^a, Yu. A. Khomutova^a, D. E. Arkhipov^b, A. A. Korlyukov^b, S. L. Ioffe^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Six-membered cyclic nitronates smoothly react with trialkylsilyl cyanide/Bu^tMe₂SiOTf or tert-butyl isocyanide/Bu^tMe₂SiOTf systems to afford 2-trialkylsilyloxy-3-cyanotetrahydro-[4H]-1,2-oxazines or δ-oxo-α-trialkylsilyloximinonitriles depending on the ring-sub- stitution pattern.

Language: English

DOI: 10.1016/j.mencom.2014.11.023

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