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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2013 Volume 23, Issue 1, Pages 19–21 (Mi mendc2598)

This article is cited in 14 papers

CuCl-Catalyzed Isomerization of gem-Chlorofluoro-Cyclopropanes into Chlorofluoroalkenes

N. V. Volchkov, M. A. Novikov, M. B. Lipkind, O. M. Nefedov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: CuCl-catalyzed isomerization of gem-chlorofluorocyclopropanes into chlorofluoroalkenes occurs as a result of the ring opening accompanied by the migration of chlorine atom. In the case of vinyl- or cyclopropyl-containing substrates, chlorofluoroalkadienes are formed.

Language: English

DOI: 10.1016/j.mencom.2013.01.006



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