Mendeleev Commun., 2013 Volume 23, Issue 1, Pages 53–55
(Mi mendc2612)
This article is cited in
13 papers
Mechanism of Methyl Methacrylate Polymerization Initiated by Benzoyl Peroxide and Ferrocene in the Presence of Oxygen Yu. I. Murinov ,
S. A. Grabovskiy ,
R. M. Islamova ,
A. R. Kuramshina ,
N. N. Kabal'nova Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation Abstract:
The role of the ferrocenium radical cation and Cp
2 Fe
+ –O• radical in the initiation of methyl methacrylate polymerization in the absence and presence of oxygen was demonstrated.
Keywords:
ferrocene, benzoyl peroxide, ferrocenium radical-cation, [μ-(peroxy-O:O′)]di-ferrocenium, oligomeric reaction center.
Language: English
DOI:
10.1016/j.mencom.2013.01.020
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