M. M. Krayushkin, A. M. Bogacheva, K. S. Levchenko, O. I. Kobeleva, T. M. Valova, V. A. Barachevskiĭ, J.-L. Pozzo, M. I. Struchkova, P. S. Shmelin, M. A. Kalik, T. K. Baryshnikova, V. N. Charushin, “Synthesis of photochromic 6-aryl-substituted bis(benzothiophenyl)- perfluorocyclopentenes by the Suzuki–Miyaura cross-coupling”, Mendeleev Commun., 2013, Volume 23, Issue 2,Pages <nobr>78–80</nobr>

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Mendeleev Commun., 2013 Volume 23, Issue 2, Pages 78–80 (Mi mendc2619)

This article is cited in 12 papers

Synthesis of photochromic 6-aryl-substituted bis(benzothiophenyl)- perfluorocyclopentenes by the Suzuki–Miyaura cross-coupling

M. M. Krayushkin^a, A. M. Bogacheva^b, K. S. Levchenko^c, O. I. Kobeleva^d, T. M. Valova^d, V. A. Barachevskiĭ^d, J.-L. Pozzo^e, M. I. Struchkova^a, P. S. Shmelin^c, M. A. Kalik^a, T. K. Baryshnikova^a, V. N. Charushin^b

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
^c Central Science Research Institute of Technology "Technomash", Moscow, Russian Federation
^d Photochemistry Center, FSRC ‘Crystallography and Photonics’, Russian Academy of Sciences, Moscow, Russian Federation
^e Institute of Molecular Sciences, University of Bordeaux, Talence, France

Abstract: The Suzuki cross-coupling of 1,2-bis(6-iodo-2-methylbenzo[b]thiophen-3-yl)hexafluorocyclopentene and (het)arylboronic acids depending on the reaction conditions affords bis- or mono-adducts. The latter on next cross-coupling with different boronic acid give unsymmetrical dihetarylethenes. Spectral-kinetic studies of the photoinduced cyclization of the compounds obtained were performed.

Language: English

DOI: 10.1016/j.mencom.2013.03.007

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