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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2013 Volume 23, Issue 3, Pages 133–134 (Mi mendc2637)

This article is cited in 6 papers

Communications

Synthesis and reactivity of the cyclohexadienyl ruthenium complex [(hhh5-C6H7)Ru(MeCN)3]+ with labile acetonitrile ligands

E. A. Trifonova, N. L. Loskutova, D. S. Perekalin, Yu. V. Nelyubina, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The UV irradiation of [(h5-C6H7)Ru(C6H6)]+ in MeCN gives the title complex, in which acetonitrile ligands are readily replaced by cyclopentadienide and tricarbollide anions; the structure of the tricarbollide derivative 1-(h5-C6H7)-12-ButNH-1,2,4,12-RuC3B8H10 was established by X-ray diffraction analysis.

Language: English

DOI: 10.1016/j.mencom.2013.05.003



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