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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2013 Volume 23, Issue 3, Pages 137–139 (Mi mendc2639)

This article is cited in 14 papers

Communications

Synthesis of a stable J-type dimer based on the 2-hydroxy- 9(10),16(17),23(24)-tri(tert-butyl)phthalocyanine zinc complex

A. Yu. Tolbina, V. E. Pushkarevab, I. O. Balashovaa, L. G. Tomilovaab

a Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Interaction of 2-hydroxy-9(10),16(17),23(24)-tri(tert-butyl)phthalocyanine with zinc acetate in the presence of lithium methoxide affords a stable J-type dimer. Its formation was simulated by density functional theory (DFT).

Keywords: Фталоцианин, синтез, комплекс, J-димер, электронная спектроскопия, ЯМР спектроскопия, DFT-study.

Language: English

DOI: 10.1016/j.mencom.2013.05.005



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