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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2013 Volume 23, Issue 4, Pages 196–198 (Mi mendc2659)

This article is cited in 4 papers

Communications

Pentakis-thiacalix[4]Arenes with Nitrile Fragments: Receptor Properties toward Cations of Some s-and d-metals and Self-assembly of Nanoscale Aggregates

A. V. Galukhina, E. A. Andreykoa, I. Kh. Rizvanovb, I. I. Stoikova

a Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
b A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: Pentakis-thiacalix[4]arenes containing thiacalix[4]arene fragments in cone, partial cone and 1,3-alternate conformations as their central core have been obtained. Their interaction with cations of s- and d-metals gives supramolecular assemblies whose composition depends on the conformation of pentakis-thiacalix[4]arenes and the nature of the ‘guests’.

Keywords: thiacalix[4]arene, multicalixarene, self-assembly, electronic spectroscopy.

Language: English

DOI: 10.1016/j.mencom.2013.07.005



© Steklov Math. Inst. of RAS, 2025