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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2013 Volume 23, Issue 4, Pages 204–205 (Mi mendc2662)

This article is cited in 11 papers

Communications

Superbase-catalyzed addition of ketones to propargyl and allenyl ethers in the KOH (KOBut)/DMSO system

E. Yu. Schmidt, N. V. Zorina, O. A. Tarasova, I. A. Ushakov, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Alkyl (het)aryl ketones undergo nucleophilic addition to propargyl or allenyl ethers in the KOH (KOBut)/DMSO system at 100°C either at terminal (giving 1:2 adducts) or internal (giving 1:1 adducts) positions of the propargyl or allenyl fragment.

Language: English

DOI: 10.1016/j.mencom.2013.07.008



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