Sh.-D. Bai, R.-Q. Liu, F. Guan, T. Wang, H.-B. Tong, J.-P. Guo, D.-Sh. Liu, “Alkyl-ended <i>ansa</i>-bis(amidinate) ligands from aliphatic primary amines and multinuclear lithium derivatives”, Mendeleev Commun., 2013, Volume 23, Issue 5,Pages <nobr>265

This article is cited in 10 papers

Communications

Alkyl-ended ansa-bis(amidinate) ligands from aliphatic primary amines and multinuclear lithium derivatives

Sh.-D. Bai^a, R.-Q. Liu^a, F. Guan^a, T. Wang^a, H.-B. Tong^a, J.-P. Guo^b, D.-Sh. Liu^a

^a Institute of Applied Chemistry, Shanxi University, Taiyuan, Shanxi, P. R. China
^b Solid Wastes Resource Utilization and Energy Saving Building Materials State Key Laboratory, Shijingshan District, Beijing, P. R. China

Abstract: A practical synthetic pathway to alkyl-ended ansa-bis(amidinate) ligands was developed via linking the freshly prepared aliphatic group substituted lithium amidinate and the subsequent deprotonation. The lithium complexes prepared by this method were characterized by NMR spectroscopy, elemental analysis and single-crystal X-ray diffraction analysis.

Keywords: aliphatic primary amine; ansa-bis(amidinate); multinuclear lithium.

Language: English

DOI: 10.1016/j.mencom.2013.09.009