Abstract:
The adsorption behaviour of a complex formed by the ammonium cation with the macrobicyclic ligand cryptand 2.2.2 ([NH4+ ⊂ 2.2.2]) at the electrode/solution interface was characterized as a function of electrode potential and the ligand concentration and quantitative parameters of the adsorbed layers of [NH4+ ⊂ 2.2.2] were obtained.