V. G. Shtamburg, O. V. Shishkin, R. I. Zubatyuk, V. V. Shtamburg, A. V. Tsygankov, A. V. Mazepa, G. K. Kadorkina, R. G. Kostyanovsky, “Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N’,N’,N’-trialkylhydrazinium salts”, Mendeleev Commun., 2013, Volume 23, Issue 5,Pages 289

This article is cited in 6 papers

Communications

Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N’,N’,N’-trialkylhydrazinium salts

V. G. Shtamburg^a, O. V. Shishkin^b, R. I. Zubatyuk^b, V. V. Shtamburg^c, A. V. Tsygankov^d, A. V. Mazepa^e, G. K. Kadorkina^f, R. G. Kostyanovsky^f

^a Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
^b STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
^c Kharkov Institute of Ecology and Social Dependence, Kharkov, Ukraine
^d State Flight Academy of Ukraine, Kirovograd, Ukraine
^e A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
^f N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: New types of 1,1,1-trialkyl-2-alkoxyhydrazinium chlorides and N-alkoxyhydrazines were obtained by reactions of N-chloro-N-alkoxy- ureas with trimethylamine or 1,4-diaza[2.2.2]bicyclooctane and by reactions of methyl N-chloro-N-methoxycarbamate with potassium salt of N-acetylbenzenesulfonylamide. The XRD studies of N,N’-bis(methoxycarbonyl)-N,N’-dimethoxyhydrazine, N’-methoxy- N’-methoxycarbonyl-N-acetylbenzenesulfonylhydrazide and 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate revealed the pyramidal configuration of the central nitrogen atoms in O–N–N geminal system, unusual elongation of N–N⁺ bond and shortening of N–OMe bond in 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate.

Language: English

DOI: 10.1016/j.mencom.2013.09.018