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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2013 Volume 23, Issue 6, Pages 356–357 (Mi mendc2714)

This article is cited in 7 papers

Communications

Synthesis of 2-cyanoacryloyl chloride and its interaction with O- and S-nucleophiles

V. A. Dyatlova, I. R. Rustamova, T. A. Grebenevaa, V. I. Maleevb, Yu. G. Gololobovb, V. V. Kireeva

a D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Reaction of 2-cyanoacrylic acid with oxalyl chloride gives quantitatively 2-cyanoacryloyl chloride capable of esterifying thiols and fluorinated alcohols.

Keywords: polymer, esterification, fluorine thio-, dithioester, 2-cyanoacryloyl chloride.

Language: English

DOI: 10.1016/j.mencom.2013.11.019



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