Mendeleev Commun., 2013 Volume 23, Issue 6, Pages 356–357
(Mi mendc2714)
This article is cited in
7 papers
Communications
Synthesis of 2-cyanoacryloyl chloride and its interaction with O- and S-nucleophiles
V. A. Dyatlov a ,
I. R. Rustamov a ,
T. A. Grebeneva a ,
V. I. Maleev b ,
Yu. G. Gololobov b ,
V. V. Kireev a a D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
Reaction of 2-cyanoacrylic acid with oxalyl chloride gives quantitatively 2-cyanoacryloyl chloride capable of esterifying thiols and fluorinated alcohols.
Keywords:
polymer, esterification, fluorine
thio-, dithioester, 2-cyanoacryloyl chloride.
Language: English
DOI:
10.1016/j.mencom.2013.11.019
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