A. S. Romanov, D. V. Muratov, P. V. Petrovskii, W. Siebert, A. R. Kudinov, “The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3”, Mendeleev Commun., 2012, Volume 22, Issue 1,Pages 13

This article is cited in 4 papers

The first triple-decker complex with the PtMe₃ fragment: CpCo(μ-1,3-C₃B₂Me₅)PtMe₃

A. S. Romanov^a, D. V. Muratov^a, P. V. Petrovskii^a, W. Siebert^b, A. R. Kudinov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Fakultaet fuer Chemie, Institut fuer Anorganische Chemie, Ruprecht-Karls-Universitaet zu Heidelberg, Germany

Abstract: The μ-diborolyl triple-decker complex CpCo(μ-1,3-C₃B₂Me₅)PtMe₃ was prepared by reaction of the sandwich anion [CpCo(1,3-C₃B₂Me₅)]–with [PtMe₃I]₄; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C₃B₂Me₅)]– and [PtMe3]+ fragments are ∼64% electrostatic and 36% covalent.

Language: English

DOI: 10.1016/j.mencom.2012.01.004

	*Supplementary materials:*
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