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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2012 Volume 22, Issue 1, Pages 13–14 (Mi mendc2720)

This article is cited in 4 papers

The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3

A. S. Romanova, D. V. Muratova, P. V. Petrovskiia, W. Siebertb, A. R. Kudinova

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Fakultaet fuer Chemie, Institut fuer Anorganische Chemie, Ruprecht-Karls-Universitaet zu Heidelberg, Germany

Abstract: The μ-diborolyl triple-decker complex CpCo(μ-1,3-C3B2Me5)PtMe3 was prepared by reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]–with [PtMe3I]4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C3B2Me5)]– and [PtMe3]+ fragments are ∼64% electrostatic and 36% covalent.

Language: English

DOI: 10.1016/j.mencom.2012.01.004



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