A. V. Artem'ev, S. F. Malysheva, B. G. Sukhov, N. A. Belogorlova, Yu. V. Gatilov, V. I. Mamatyuk, N. K. Gusarova, “Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine”, Mendeleev Commun., 2012, Volume 22, Issue 1,Pages <nobr>18–20</nobr>

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Mendeleev Commun., 2012 Volume 22, Issue 1, Pages 18–20 (Mi mendc2722)

This article is cited in 12 papers

Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine

A. V. Artem'ev^a, S. F. Malysheva^a, B. G. Sukhov^a, N. A. Belogorlova^a, Yu. V. Gatilov^b, V. I. Mamatyuk^b, N. K. Gusarova^a

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Redox reaction between alkali metal diselenophosphinates R2P(Se)SeM (M = Na, K) and elemental iodine in a 2:1 molar ratio (1,4-dioxane, room temperature, 2min) gives bis(diorganylselenophosphoryl)selenides [R₂P(Se)]₂Se and bis(diorganylselenophosphoryl) triselenides [R₂P(Se)]₂Se₃ in 87–90% total yields.

Language: English

DOI: 10.1016/j.mencom.2012.01.006

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