B. A. Trofimov, E. Yu. Schmidt, E. V. Skital’tseva, I. A. Bidusenko, N. V. Zorina, A. I. Mikhaleva, “Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples”, Mendeleev Commun., 2012, Volume 22, Issue 2,Pages <nobr>62

This article is cited in 8 papers

Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples

B. A. Trofimov, E. Yu. Schmidt, E. V. Skital’tseva, I. A. Bidusenko, N. V. Zorina, A. I. Mikhaleva

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: 1-Ethynylcyclohexanol and 1-ethynylcycloheptanol are O-vinylated with acetylene in KOH/DMSO superbase system (90°C, autoclave, initial acetylene pressure of 14 atm, 1h) to afford the corresponding vinyl ethers in 40 and 34% yields, respectively.

Language: English

DOI: 10.1016/j.mencom.2012.03.002