V. G. Shtamburg, A. V. Tsygankov, O. V. Shishkin, R. I. Zubatyuk, V. V. Shtamburg, M. V. Gerasimenko, A. V. Mazepa, R. G. Kostyanovsky, “1-Alkoxyamino-4-dimethylaminopyridinium derivatives as new representatives of O–N–N+ geminal systems and their structure†”, Mendeleev Commun., 2012, Volume 22, Issue 2,Pages <nobr>92

This article is cited in 6 papers

1-Alkoxyamino-4-dimethylaminopyridinium derivatives as new representatives of O–N–N+ geminal systems and their structure†

V. G. Shtamburg^a, A. V. Tsygankov^b, O. V. Shishkin^c, R. I. Zubatyuk^c, V. V. Shtamburg^d, M. V. Gerasimenko^a, A. V. Mazepa^e, R. G. Kostyanovsky^f

^a Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
^b State Flight Academy of Ukraine, Kirovograd, Ukraine
^c STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
^d Department of Chemistry, National Technical University 'Kharkov Polytechnic Institute', Kharkov, Ukraine
^e A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
^f N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: N-Alkoxy-N-(4-dimethylaminopyridin-1-ium-1-yl)-substituted ureas, benzamides and N-tert-alkylamines were prepared by the reac tion of the corresponding (N-chloro-N-alkoxy)amino compounds with 4-dimethylaminopyridine. The XRD study of N-alkoxy-N-(4-dimethylaminopyridin-1-ium-1-yl)ureas has revealed the high pyramidality of the central nitrogen atom in O–N–N+ geminal system.

Language: English

DOI: 10.1016/j.mencom.2012.03.014

	*Supplementary materials:*
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