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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2012 Volume 22, Issue 3, Pages 129–131 (Mi mendc2763)

This article is cited in 9 papers

Pyridinium o-iodoxybenzoate as a Safe form of a Famous Oxidant

I. M. Kumanyaev, M. A. Lapitskaya, L. L. Vasiljeva, K. K. Pivnitsky

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The stable pyridinium salt of o-iodoxybenzoic acid (PIBX) that is easy to obtain can serve as a convenient substitute of IBX as an oxidant. PIBX is safer, has neutral properties behaves as an equivalent to IBX in the oxidation of alcohols to ketones or aldehydes in polar solvents (DMF, DMSO), and provides higher oxidation rate in THF due to better solubility.

Language: English

DOI: 10.1016/j.mencom.2012.05.004



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