V. G. Shtamburg, A. V. Tsygankov, O. V. Shishkin, R. I. Zubatyuk, B. V. Uspensky, V. V. Shtamburg, A. V. Mazepa, R. G. Kostyanovsky, “The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide”, Mendeleev Commun., 2012, Volume 22, Issue 3,Pages <nobr>164

This article is cited in 13 papers

The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide

V. G. Shtamburg^ab, A. V. Tsygankov^c, O. V. Shishkin^d, R. I. Zubatyuk^d, B. V. Uspensky^b, V. V. Shtamburg^b, A. V. Mazepa^e, R. G. Kostyanovsky^f

^a Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
^b Department of Chemistry, National Technical University 'Kharkov Polytechnic Institute', Kharkov, Ukraine
^c State Flight Academy of Ukraine, Kirovograd, Ukraine
^d STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
^e A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
^f N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The XRD study of N-chloro-N-methoxy-4-nitrobenzamide revealed the high pyramidality degree of its amide nitrogen atom in O–N–Cl moiety. N-Chloro-N-methoxy-4-nitrobenzamide reacts with AcONa in MeCN selectively forming N-acetoxy-N-methoxy-4-nitrobenzamide, whereas its methanolysis in the presence of AcONa yields N,N’-bis(4-nitrobenzoyl)-N,N’-dimethoxyhydrazine.

Language: English

DOI: 10.1016/j.mencom.2012.05.019