E. E. Karslyan, A. I. Konovalov, A. O. Borissova, P. V. Petrovskii, A. R. Kudinov, “[2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+”, Mendeleev Commun., 2012, Volume 22, Issue 4,Pages 189

This article is cited in 3 papers

[2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C₅Me₄CH₂OMe)Ru(η⁶-C₁₂H₈)]⁺

E. E. Karslyan, A. I. Konovalov, A. O. Borissova, P. V. Petrovskii, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The [2+2] photodimerization of the complex [(C₅Me₄CH₂OMe)Ru(η⁶-C₁₂H₈)]⁺ under visible-light irradiation leads to a mixture of the head-to-head heptacyclene products [(μ-η⁶: η⁶-C₂₄H₁₆)Ru₂(C₅Me₄CH₂OMe)₂]²⁺ (syn- and anti-) with the predominant formation of the syn-isomer; the structures of both isomers were established by X-ray diffraction analysis.

Language: English

DOI: 10.1016/j.mencom.2012.06.005

	*Supplementary materials:*
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