E. V. Ilyakina, A. I. Poddel'sky, V. K. Cherkasov, G. A. Abakumov, “Binding of NO by Nontransition Metal Complexes”, Mendeleev Commun., 2012, Volume 22, Issue 4,Pages <nobr>208

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Binding of NO by Nontransition Metal Complexes

E. V. Ilyakina, A. I. Poddel'sky, V. K. Cherkasov, G. A. Abakumov

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation

Abstract: The first example of nitric oxide fixation by nontransition metal complexes was found: lead(ii) and zinc(ii) catecholato complexes readily react with nitric oxide to give the corresponding nitrosyl-containing mono-o-semiquinonates; the process of binding and transfer of NO can be easily monitored by EPR spectroscopy.

Keywords: redox-active ligands, catecholate, lead(II), zinc(II), NO binding, EPR.

Language: English

DOI: 10.1016/j.mencom.2012.06.013

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