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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2012 Volume 22, Issue 5, Pages 270–272 (Mi mendc2816)

This article is cited in 16 papers

Electrochemical Azolation of N-substituted Pyrroles: A New Case in SNH(An) Reactions

V. L. Sigacheva, V. A. Kokorekin, Yu. A. Strelenko, S. V. Neverov, V. A. Petrosyan

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Potentiostatic electrolysis (divided cell, anode compartment) of 1-methyl- and 1-phenylpyrroles in the presence of sodium 4-nitro-pyrazolate and sodium 3-nitropyrazolate in MeCN/MeOH gave the corresponding 2-(azol-1-yl)pyrroles in 20–43% current and substance yields.

Language: English

DOI: 10.1016/j.mencom.2012.09.015



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