T. V. Magdesieva, O. M. Nikitin, E. V. Zolotukhina, V. A. Zinovieva, M. A. Vorotyntsev, “Palladium–Polypyrrole Nanoparticles-Catalyzed Sonogashira Coupling”, Mendeleev Commun., 2012, Volume 22, Issue 6,Pages <nobr>305

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Palladium–Polypyrrole Nanoparticles-Catalyzed Sonogashira Coupling

T. V. Magdesieva^a, O. M. Nikitin^a, E. V. Zolotukhina^bc, V. A. Zinovieva^c, M. A. Vorotyntsev^abc

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^c Universite de Bourgogne, LIMSAG UMR 5633, Faculte des Sciences, Dijon, France

Abstract: Palladium nanoparticles were encapsulated into polypyrrole globules via one-step one-pot redox reaction between tetraamminepal- ladium(ii) dichloride and pyrrole in water. Such a material is an active catalyst for the Sonogashira coupling of iodo- and bromo- arenes.

Language: English

DOI: 10.1016/j.mencom.2012.11.008