K. P. Birin, D. S. Dunin, M. V. Tolstykh, V. Yu. Kotov, “Strong Negative Synergism of Ion Pair Extinction Coefficients in Chloroform–Acetone and Methylene Dichloride–Acetone Mixtures”, Mendeleev Commun., 2012, Volume 22, Issue 6,Pages <nobr>320

This article is cited in 4 papers

Strong Negative Synergism of Ion Pair Extinction Coefficients in Chloroform–Acetone and Methylene Dichloride–Acetone Mixtures

K. P. Birin^a, D. S. Dunin^b, M. V. Tolstykh^b, V. Yu. Kotov^b

^a A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Institute of Natural Sciences, Moscow City Teacher’s Training University, Moscow, Russian Federation

Abstract: The heteroselective preferential solvation of the iodides of N-heterocyclic aromatic cations in acetone–chloroalkane (chloroform and dichloromethane) binary mixtures results in not only a shift in the maxima of outer-sphere charge transfer absorption bands but also a considerable decrease in the molar extinction coefficients of ion pairs.

Language: English

DOI: 10.1016/j.mencom.2012.11.014