RUS  ENG
Full version
JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2011 Volume 21, Issue 1, Pages 17–18 (Mi mendc2850)

This article is cited in 10 papers

Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives

N. K. Gusarova, S. I. Verkhoturova, T. I. Kazantseva, V. L. Mikhailenko, S. N. Arbuzova, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: Phosphine, generated from red phosphorus in the system KOH–H2O–toluene, reacts with vinyl ethers under radical initiation (AIBN, dioxane, 78–80°C, atmospheric pressure) to give tris(2-organyloxyethyl)phosphines, which are transformed to the corresponding phosphine chalcogenides (in up to 73% isolated yield) via the reactions with air oxygen, elemental sulfur or selenium.

Language: English

DOI: 10.1016/j.mencom.2011.01.007



© Steklov Math. Inst. of RAS, 2025