D. S. Perekalin, E. E. Karslyan, A. O. Borissova, A. R. Kudinov, “Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+”, Mendeleev Commun., 2011, Volume 21, Issue 2,Pages 82

This article is cited in 13 papers

Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C₁₀H₈)]⁺

D. S. Perekalin, E. E. Karslyan, A. O. Borissova, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The replacement of naphthalene ligand in the ruthenium complex [CpRu(C₁₀H₈)]⁺ by halide anions in the presence of 1,5-cyclooctadiene (cod) or norbornadiene (nbd) gives important synthetic precursors CpRu(cod)X and CpRu(nbd)X (X=Cl, Br, I) in 60–90% yield; the structure of CpRu(nbd)Br was determined by X-ray diffraction.

Language: English

DOI: 10.1016/j.mencom.2011.03.007

	*Supplementary materials:*
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