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JOURNALS // Mendeleev Communications // Archive
Mendeleev Commun., 2011 Volume 21, Issue 3, Pages 140–141 (Mi mendc2893)
Triethylsilyl triflate-promoted skeletal rearrangement of bottrospicatols

S. A. Torosyan, F. A. Gimalova, R. F. Valeev, M. S. Miftakhov

Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: Treatment of diastereomeric (1R,5R,6R)- and (1R,5R,6S)-6-hydroxymethyl-2,6-dimethyl-7-oxabicyclo[3.2.1]oct-2-enes with Et3SiOTf leads to scalemic (1R,5R,6R)- and (1R,5R,6S)-6-hydroxy-2,6-dimethyl-8-oxabicyclo[3.3.1]non-2-enes.

Language: English

DOI: 10.1016/j.mencom.2011.04.008


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