I. D. Sorokin, V. I. Feldman, O. L. Mel'nikova, V. I. Pergushov, D. A. Tyurin, M. Ya. Melnikov, “The nature and photochemistry of 2,2-dimethyloxirane radical cations in freonic matrices at 77K”, Mendeleev Commun., 2011, Volume 21, Issue 3,Pages <nobr>155

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The nature and photochemistry of 2,2-dimethyloxirane radical cations in freonic matrices at 77K

I. D. Sorokin, V. I. Feldman, O. L. Mel'nikova, V. I. Pergushov, D. A. Tyurin, M. Ya. Melnikov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The X-ray irradiation of 2,2-dimethyloxirane in freonic matrices at 77K results in the trapping of a cyclic radical cation form, presumably, complexed with a matrix molecule, which transforms into a C-centered distonic radical cation under the action of light.

Language: English

DOI: 10.1016/j.mencom.2011.04.015