L. N. Pankratova, E. V. Saenko, V. l. Bugaenko, V. V. Makhlyarchuk, “Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes”, Mendeleev Commun., 2011, Volume 21, Issue 3,Pages <nobr>157

This article is cited in 6 papers

Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes

L. N. Pankratova^a, E. V. Saenko^a, V. l. Bugaenko^b, V. V. Makhlyarchuk^c

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.I. Alikhanov Institute for Theoretical and Experimental Physics, National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
^c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: As found by EPR spectroscopy, the decay of methyl radicals in the test compounds upon X-ray irradiation at 77K resulted from radical-center transfer rather than radical combination; the rate constants of decay of methyl radicals in polydimethylsiloxane and its structural analog dimethylsilanediol were almost the same.

Language: English

DOI: 10.1016/j.mencom.2011.04.016