M. B. Berezin, E. V. Antina, N. A. Dudina, I. S. Bushmarinov, M. Yu. Antipin, L. A. Antina, G. B. Guseva, “Synthesis, structure and fluorescence of a zinc(ii) chelate complex with bis(2,4,7,8,9-pentamethyldipyrrolylmethen-3-yl)methane”, Mendeleev Commun., 2011, Volume 21, Issue 3,Pages <nobr>168

This article is cited in 38 papers

Synthesis, structure and fluorescence of a zinc(ii) chelate complex with bis(2,4,7,8,9-pentamethyldipyrrolylmethen-3-yl)methane

M. B. Berezin^a, E. V. Antina^a, N. A. Dudina^a, I. S. Bushmarinov^b, M. Yu. Antipin^b, L. A. Antina^a, G. B. Guseva^a

^a G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The crystal structure and spectral properties of new Zn(ii) chelate complex with bis(2,4,7,8,9-pentamethyldipyrrolylmethen-3-yl)methane were determined by single-crystal X-ray diffraction, ¹H NMR, UV and IR spectroscopy; a sufficiently high quantum yield of fluorescence in nonpolar solvents, a long-wavelength emission maximum and good photostability of the complex were demonstrated.

Keywords: bis(dipyrrolylmethene), synthesis, complex, double helix, crystal structure, X-ray diffraction, spectral properties.

Language: English

DOI: 10.1016/j.mencom.2011.04.020