M. B. Gazizov, R. A. Khairullin, A. A. Minnikhanova, A. I. Alekhina, R. Z. Musin, O. G. Sinyashin, “Phosphorylated aziridinium salts: synthesis and ring opening with nucleophiles”, Mendeleev Commun., 2011, Volume 21, Issue 4,Pages <nobr>198–200</nobr>

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Mendeleev Commun., 2011 Volume 21, Issue 4, Pages 198–200 (Mi mendc2915)

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Phosphorylated aziridinium salts: synthesis and ring opening with nucleophiles

M. B. Gazizov^a, R. A. Khairullin^a, A. A. Minnikhanova^a, A. I. Alekhina^a, R. Z. Musin^b, O. G. Sinyashin^b

^a Kazan National Research Technological University, Kazan, Russian Federation
^b A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: Treatment of 1-tert-butyl-2-dimethoxyphosphoryl-3,3-dimethylaziridine with picric, perchloric or fluoboric acid affords the stable corresponding aziridinium salts, which are prone to undergo ring opening on reaction with alcohols, carboxylate and thiocyanate ions.

Language: English

DOI: 10.1016/j.mencom.2011.07.009

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