R. M. Kagirov, A. V. Voloshin, M. K. Kadirov, I. R. Nizameev, O. G. Sinyashin, D. G. Yakhvarov, “Selective synthesis of nanosized palladium phosphides from white phosphorus”, Mendeleev Commun., 2011, Volume 21, Issue 4,Pages <nobr>201

This article is cited in 12 papers

Selective synthesis of nanosized palladium phosphides from white phosphorus

R. M. Kagirov^a, A. V. Voloshin^b, M. K. Kadirov^a, I. R. Nizameev^a, O. G. Sinyashin^a, D. G. Yakhvarov^a

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Institute of Physics, Kazan Federal University, Kazan, Russian Federation

Abstract: The reaction of white phosphorus with the palladium(0) complex [Pd₂(dba)₃] (dba is dibenzylideneacetone) leads to stable associates [Pd(P₄)]_n. The coordination polymer obtained is stabilized in a solid state via the formation of nanosized palladium phosphides Pd₃P₂ and Pd₆P with average particle sizes of 140 and 65nm, respectively.

Language: English

DOI: 10.1016/j.mencom.2011.07.010