RUS  ENG
Full version
JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2011 Volume 21, Issue 5, Pages 247–249 (Mi mendc2932)

This article is cited in 6 papers

Molecular and crystal structures of hetero-analogues of bicyclo[3.3.1]nonane with nitrogen and sulfur atoms

O. N. Zefirovaab, N. N. Moiseevaa, E. V. Nurievaa, T. P. Trofimovaa, A. N. Proshinb, Yu. L. Slovokhotovac

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The X-ray molecular structures of bridgehead heterocycles, namely, 3-thia-1-azabicyclo[3.3.1]nonane-2-thione, 1,3-diazabicyclo[3.3.1]nonane-2-thione, (2Z)-2-(N-benzoylimino)-3-thia-1-azabicyclo[3.3.1]nonane and (2Z)-2-(3,4-dichlorophenylimino)-3-thia-1-azabicyclo[3.3.1]nonane were determined and their molecular packing in the crystals was revealed. The rings distortion in the bridgehead core was evaluated by the calculation of ZP and CP puckering parameters.

Language: English

DOI: 10.1016/j.mencom.2011.09.005



© Steklov Math. Inst. of RAS, 2025