M. V. Tsikalova, S. V. Zheludkov, E. V. Vorontsov, V. V. Bashilov, K. K. Babievskii, V. I. Sokolov, Yu. N. Novikov, “Optically active rhodium and iridium C60 complexes containing the enantiomeric ligand (+)DIOP: (η2-C60)MH(CO)[(+)DIOP] (M=Rh, Ir)”, Mendeleev Commun., 2011, Volume 21, Issue 5,Pages 256

This article is cited in 4 papers

Optically active rhodium and iridium C₆₀ complexes containing the enantiomeric ligand (+)DIOP: (η²-C₆₀)MH(CO)[(+)DIOP] (M=Rh, Ir)

M. V. Tsikalova, S. V. Zheludkov, E. V. Vorontsov, V. V. Bashilov, K. K. Babievskii, V. I. Sokolov, Yu. N. Novikov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The fullerene–metal complexes (η²-C₆₀)MH(CO)[(+)DIOP] (M=Ir, Rh) have been prepared by the exchange reaction of PPh₃ in corresponding (η²-C₆₀)MH(CO)(PPh₃)₂ for the chelate optically active ligand (+)DIOP [(+)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)ethane] and their structures assigned.

Language: English

DOI: 10.1016/j.mencom.2011.09.008