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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2011 Volume 21, Issue 5, Pages 274–276 (Mi mendc2942)

This article is cited in 2 papers

Mechanism of H2-promoted oxidation of nitrogen monoxide over Ag/Al2O3

N. A. Sadokhinaa, A. V. Bukhtiyarovb, A. I. Mytarevaa, R. I. Kvonb, V. I. Bukhtiyarovb, A. Yu. Stakheeva

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: H2-promoted oxidation of NO to NO2 over Ag/Al2O3 proceeds via two-step mechanism: (1) formation of surface nitrate species, and (2) reduction of this species with NO. Hydrogen plays a crucial role at the first step.

Language: English

DOI: 10.1016/j.mencom.2011.09.015



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