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JOURNALS
// Mendeleev Communications
// Archive
Mendeleev Commun.,
2011
Volume 21,
Issue 6,
Pages
323–325
(Mi mendc2959)
This article is cited in
12
papers
Superelectrophilic
sp
3
C–H carbonylation of
n
-octyl acetate as a way to new bifunctional
neo
-octanes
I. S. Akhrem
,
D. V. Avetisyan
,
L. V. Afanas'eva
,
A. V. Orlinkov
,
N. D. Kagramanov
,
P. V. Petrovskii
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
Carbonylation of
n
-octyl acetate in the presence of CBr
4
·2AlBr
3
followed by treatment with nucleophiles such as alcohols, amines or (het)arenes affords 7-acetoxy-2,2-dimethylheptanoyl-containing products.
Language:
English
DOI:
10.1016/j.mencom.2011.11.010
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