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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2011 Volume 21, Issue 6, Pages 323–325 (Mi mendc2959)

This article is cited in 12 papers

Superelectrophilic sp3 C–H carbonylation of n-octyl acetate as a way to new bifunctional neo-octanes

I. S. Akhrem, D. V. Avetisyan, L. V. Afanas'eva, A. V. Orlinkov, N. D. Kagramanov, P. V. Petrovskii

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Carbonylation of n-octyl acetate in the presence of CBr4·2AlBr3 followed by treatment with nucleophiles such as alcohols, amines or (het)arenes affords 7-acetoxy-2,2-dimethylheptanoyl-containing products.

Language: English

DOI: 10.1016/j.mencom.2011.11.010



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