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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2010 Volume 20, Issue 1, Pages 4–6 (Mi mendc2971)

This article is cited in 3 papers

Synthesis and structure of pyrimidinophanes with a sulfur atom in the spacer

A. E. Nikolaev, V. E. Semenov, O. A. Lodochnikova, Sh. K. Latypov, V. S. Reznik

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: The cyclization of 1,3-bis(ω-bromoalkyl)uracils with sodium sulfide led to pyrimidinophanes, containing one uracil unit and an S atom in the spacer, macrocyclic structure was confirmed by X-ray data; the S atom in bridge can be oxidized into sulfoxide or sulfone or converted into sulfonium ion.

Keywords: macrocycle, pyrimidinophane, uracil, cyclization, sulfonium salts.

Language: English

DOI: 10.1016/j.mencom.2010.01.002



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