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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2010 Volume 20, Issue 1, Pages 12–14 (Mi mendc2974)

This article is cited in 11 papers

Impedance spectroscopy study of lithium ion diffusion in a new cathode material based on vanadium pentoxide

D. A. Semenenkoa, T. L. Kulovab, A. M. Skundinb, D. M. Itkisa, E. A. Pomerantsevaa, E. A. Goodilinac, Yu. D. Tret'yakovac

a Department of Materials Science, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: The high discharge capacity (ca. 380 mAh g−1 in the first cycle) and diffusion coefficients of Li+ ranging from ∼10−10 to ∼10−9cm2 s−1 were estimated from electrochemical experiments for the new composite material based on vanadium pentoxide xerogel and carbon nanotubes synthesized using freeze-drying technology demonstrating that it can be used in cathodes for advanced lithium-ion batteries.

Keywords: vanadium pentoxide, xerogel, cathode materials, lithium ion batteries.

Language: English

DOI: 10.1016/j.mencom.2010.01.005



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